Page 61 - 《精细化工》2020年第12期

第 12 期 罗晓菲，等: 多孔材料在催化 CO 2 与环氧化物环加成反应中的研究进展 ·2423·

人们已经对无机多孔材料进行了深入的研究并取得 [9] WU Z J, DAI J T, TANG L Y, et al. Sorbitol-based aqueous cyclic
carbonate dispersion for waterborne nonisocyanate polyurethane
较大进步，但在对无机多孔材料孔壁及孔表面功能
coatings via an environment-friendly route[J]. Journal of Coatings
化改性方面仍存在一定的困难，解决此难题提高催 Technology and Research, 2019, 16(3): 721-732.
化活性是未来的研究热点。 [10] BEHARAJ A, EKLADIOUS I, GRINSTAFF M W. Poly (alkyl
glycidate carbonate)s as degradable pressure-sensitive adhesives[J].
POPs 作为 CO 2 环加成反应的催化剂潜力巨大。 Angewandte Chemie, 2019, 131(5): 1421-1425.
结构的多样性、可设计性、可剪裁性使其在材料制 [11] KINAGE A K , GUPTE S P , CHATURVEDI R K , et al. Highly
selective synthesis of mono-ethylene glycol phenyl ethers via
备方面占有优势，均匀的孔径以及高比表面积和表
hydroxyalkoxylation of phenols by cyclic carbonates using large pore
面碱性位（氮和其他杂元素）在 CO 2 捕获和转化中 zeolites[J]. Catalysis Communications, 2008, 9(7):1649-1655.
起关键作用，结晶或无定形的 POPs 均显示出良好 [12] PASTUSIAK M, JAWORSKA J, KAWALEC M, et al. Obtaining
aliphatic branched polycarbonates via simple copolymerization of
的 CO 2 捕获和转化能力，解决了常规非均相催化剂 trimethylene carbonate with cyclic carbonate containing pendant ester
反应活性低和效率低的问题。然而，与用于捕获和 groups[J]. Journal of Polymer Science Part A: Polymer Chemistry,
2017, 55(5): 808-819.
固定 CO 2 的 MOFs 相比，功能性 POPs 的开发研究
[13] YUEN A Y, LOPEZ-MARTINEZ E, GOMEZ-BENGOA E, et al.
还很落后，应充分考虑功能单体的设计和目标催化 Preparation of biodegradable cationic polycarbonates and hydrogels
剂的合成策略，探索设计更有效的 POPs。 through the direct polymerization of quaternized cyclic carbonates[J].
ACS Biomaterials Science & Engineering, 2017, 3(8): 1567-1575.
MOFs 非均相催化剂的研究开发非常迅速，在 [14] CASTRO-OSMA J A, LAMB K J, NORTH M. Cr (salophen) complex
有或没有助催化剂的情况下，MOFs 中暴露的路易 catalyzed cyclic carbonate synthesis at ambient temperature and
pressure[J]. ACS Catalysis, 2016, 6(8): 5012-5025.
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可在 MOFs 催化剂中引入路易斯碱性基团来同时捕
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获和活化 CO 2 ，从而促进催化反应。此外，MOFs catalyst system for coupling reaction of CO 2 and epoxides[J]. Journal
具有的晶体性质、可调节的成分和孔结构，可以提 of Molecular Catalysis A: Chemical, 2007, 261(1): 12-15.
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供一个重要的平台来研究主体-客体相互作用与催 carbon dioxide to organic carbonates over heterogeneous catalysts[J].
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[18] XIAO L F, LI F W, PENG J J, et al. Immobilized ionic liquid/zinc
为环状碳酸酯方面取得了较大进展，但仍需要系统
chloride: Heterogeneous catalyst for synthesis of cyclic carbonates
开发可在温和条件下不使用助催化剂、热稳定性较 from carbon dioxide and epoxides[J]. Journal of Molecular Catalysis
好的多孔非均相催化剂以应用于工业方面。 A: Chemical, 2006, 253(1/2): 265-269.
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